Rubrene-Directed Structural Transformation of Fullerene (C60) Microsheets to Nanorod Arrays with Enhanced Photoelectrochemical Properties

Rubrene-Directed Structural Transformation of Fullerene (C60) Microsheets to Nanorod Arrays with Enhanced Photoelectrochemical Properties

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One-dimensional (1D) nanostructures possess huge potential in electronics and optoelectronics, but the axial alignment of such 1D structures is still a challenging task.Herein, we report a simple method that enables two-dimensional (2D) C60 microsheets to evolve into highly ordered nanorod arrays using rubrene as a structure-directing agent.The structural transformation is accomplished by adding droplets of rubrene-m-xylene solution onto C60 microsheets and allowing the m-xylene solvent to evaporate naturally.

In sharp contrast, when rubrene is absent from m-xylene, randomly oriented C60 nanorods are produced.Spectroscopic and microscopic characterizations collectively indicate a rather plausible transformation mechanism that the close Sustainable waste management: international experience for Ukraine regions lattice match allows the epitaxial growth of rubrene on C60 microsheets, followed by Effects of compression running pants and treadmill running stages on knee proprioception and fatigue-related physiological responses in half-marathon runners the reassembly of dissolved C60 along the aligned rubrene due to the intermolecular charge-transfer (CT) interactions, leading to the formation of ordered nanorod arrays.Due to the aligned structures and the CT interactions between rubrene and C60, the photocurrent density of the nanorod arrays is improved by 31.

2% in the UV region relative to the randomly oriented counterpart.This work presents a facile and effective strategy for the construction of ordered fullerene nanorod arrays, providing new ideas for the alignment of fullerene and other relevant organic microstructures.